Skip to main content

NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.

Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.

U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Mechanism of Gas-Phase Hydrogenation of Alicyclic Ketones on Iron Catalyst: Effective

Published

Author(s)

Anzor I. Mikaia, Leonid S. Glebov, Vladimir Smetanin, Vladimir G. Zaikin, George A. Kliger, Sergai Loktev

Abstract

Mechanism of gas phase hydrogenation of cyclopentanone and cyclohexanone over a fused iron catalyst by “Reaction GC-MS” presented. The study involves on-line deuterogenation and on-column silylation of reaction products. It is established that cyclanone hydrogenation reactions proceed both via ketonic and enolic mechanisms.
Citation
Journal of Catalysis
Volume
93
Issue
1

Keywords

"Reaction GC-MS", "Cyclopentanone", "Cyclohexanone", "Mechanism", "Enolic", "ketonis"

Citation

Mikaia, A. , Glebov, L. , Smetanin, V. , Zaikin, V. , Kliger, G. and Loktev, S. (1985), Mechanism of Gas-Phase Hydrogenation of Alicyclic Ketones on Iron Catalyst: Effective, Journal of Catalysis, [online], https://doi.org/10.1016/0021-9517(85)90152-6 (Accessed October 14, 2025)

Issues

If you have any questions about this publication or are having problems accessing it, please contact [email protected].

Created May 1, 1985, Updated January 27, 2020
Was this page helpful?