Stefanoski, S.
, Martin, J.
and Nolas, G.
(2010),
Low temperature transport properties and heat capacity of single-crystal Na8Si46, Journal of Physics Condensed Matter, [online], https://doi.org/10.1088/0953-8984/22/48/485404, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=906133
(Accessed December 12, 2024)
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Low temperature transport properties and heat capacity of single-crystal Na8Si46
Published
Author(s)
Stevce Stefanoski, , George S. Nolas
Abstract
The low temperature thermal conductivity, resistivity, and Seebeck coefficient of single-crystal Na8Si46 are investigated revealing the intrinsic low temperature transport properties of this material. Metallic conduction is observed, with a higher residual resistance ratio than any other known type I clathrate. Heat capacity together with thermal conductivity provide insight into the Na disorder inside the polyhedra formed by the Si framework. Single-crystal structural refinement and thermal property analyses reveal anisotropic disorder for Na inside the tetrakaidecahedra due to a reduction in the symmetry inside these polyhedra, unlike that for Na inside the dodecahedra.Citation
Journal of Physics Condensed Matter
Pub Type
Journals
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Keywords
clathrate, transport properties, Seebeck coefficient
Citation
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Created November 17, 2010, Updated October 12, 2022