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The presentation provides a historical perspective of refrigerant evolution, a summary of the screening process for refrigerants with a low global warming potential (GWP), and a review of available low-GWP options for main applications, including selection decisions made, where applicable. In spite an extensive research efforts, rather limited replacement options exist for unitary air conditioning (R-410A replacements) and commercial refrigeration (R-404A replacements). Several hydrofluoroolefins (HFOs), successfully used in low- and medium-pressure systems, do not have a normal boiling point low enough for use in these high-pressure applications, unless they are blended with low-temperature boiling fluids, which tend to have a much higher GWP. The presentation also discusses the GWP/flammability trade-off and the latest alternative low-GWP fluids under consideration. Future product offerings will undergo increasing market fragmentation with multiple refrigerants used in a given application depending on regional preferences and regulations, cost, and equipment size.
Conference Dates
November 22-26, 2021
Conference Location
Flioranopolis, SC, BR
Conference Title
COBEM 2021, 26 International Congress of Mechanical Engineering, Brazil.
air conditioning, coefficient of performance, global warming potential, volumetric capacity, refrigeration
Citation
Domanski, P.
(2021),
Low-GWP Refrigerants: Options and Decisions, COBEM 2021, 26 International Congress of Mechanical Engineering, Brazil., Flioranopolis, SC, BR, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=933752
(Accessed June 30, 2025)