Swetz, D.
, Doriese, W.
, Fowler, J.
, Gard, J.
, Hilton, G.
, Morgan, K.
, O'Neil, G.
and Ullom, J.
(2017),
L-Edge Spectroscopy of Dilute, Radiation-Sensitive Systems Using a Transition-Edge-Sensor Array, Journal of Physical Chemistry B, [online], https://doi.org/10.1063/1.5000755
(Accessed July 3, 2025)
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L-Edge Spectroscopy of Dilute, Radiation-Sensitive Systems Using a Transition-Edge-Sensor Array
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Abstract
We present X-ray absorption spectroscopy and resonant inelastic X-ray scattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueous ferricyanide. These measurements demonstrate the ability of high-throughput transition- edge-sensor (TES) spectrometers to access the rich soft X-ray (1002000 eV) spectroscopy regime for dilute and radiation-sensitive samples. Our low-concentration data are in agreement with high-concentration measurements recorded by conventional grating-based spectrometers. These results show that soft X-ray RIXS spectroscopy acquired by high- throughput TES spectrometers can be used to study the local electronic structure of dilute metal- centered complexes relevant to biology, chemistry and catalysis. In particular, TES spectrometers have a unique ability to characterize frozen solutions of radiation- and temperature-sensitive samples.Citation
Journal of Physical Chemistry B
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Journals
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Keywords
X-ray spectroscopy, X-ray Microcalorimeter, Transition-Edge Sensors, Resonant Inelastic X-ray Scattering
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Created December 7, 2017, Updated November 10, 2018