Gentle recoil synthesis of free-radical clusters: Ar-SH via unimolecular photolysis of Ar-H2S
S R. Mackenzie, O Votava, J B. Fair, David Nesbitt
A novel method for the generation of free-radical clusters is presented based on UV photolysis of the corresponding closed-shell complex. Illusions is provided by the LIF detection of Ar-SH produced by 248 nm excitation of Ar-H2S. A simple ballistic model for this surprisingly efficient process is shown to account for the main observations.
, Votava, O.
, Fair, J.
and Nesbitt, D.
Gentle recoil synthesis of free-radical clusters: Ar-SH via unimolecular photolysis of Ar-H<sub>2</sub>S, Journal of Chemical Physics
(Accessed June 6, 2023)