Mackenzie, S.
, Votava, O.
, Fair, J.
and Nesbitt, D.
(2021),
Gentle recoil synthesis of free-radical clusters: Ar-SH via unimolecular photolysis of Ar-H<sub>2</sub>S, Journal of Chemical Physics (Accessed May 2, 2026)
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Gentle recoil synthesis of free-radical clusters: Ar-SH via unimolecular photolysis of Ar-H2S
Published
Author(s)
S R. Mackenzie, O Votava, J B. Fair,
Abstract
A novel method for the generation of free-radical clusters is presented based on UV photolysis of the corresponding closed-shell complex. Illusions is provided by the LIF detection of Ar-SH produced by 248 nm excitation of Ar-H2S. A simple ballistic model for this surprisingly efficient process is shown to account for the main observations.Citation
Journal of Chemical Physics
Pub Type
Journals
Keywords
free radical clusters, open-shell complex, photolysis
Citation
Issues
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Created October 12, 2021