The Direct Production of CO(v=1-9) in the Reaction of O (P-3) With the Ethyl Radical

Published

September 1, 2000

Author(s)

J P. Reid, T P. Marcy, S Kuehn, S R. Leone

Abstract

A new product channel that yields vibrationally excited CO(Ņ=1-9) in the reaction of the ethyl radical with O(³P) is experimentally observed by time-resolved Fourier transform infrared emission spectroscopy. The branching ratios for the different vibrational states are estimated to be 0.21 0.06, 0.27 0.03, 0.14 0.02, 0.08 0.02, 0.07 0.02, 0.06 0.02, 0.05 0.02, and 0.05 0.02 for Ņ=1-9, respectively. Previously, only the CH₃+H₂CO, CH₃CHO+H, and C₂H₄ + OH channels were known. Kinetics tests are provided to verify that the CO is produced directly in the reaction and not from secondary chemistry. The two possible new product channels are CO+CH₄+H and CO+CH₃+H₂. The implications of this previously unexplored reaction channel for combustion chemistry and the possible mechanisms for this reaction are discussed.

Citation

Journal of Chemical Physics

Volume

113

Issue

No. 11

Pub Type

Journals

Keywords

chemical dynamics, kinetics combustion

Citation

Reid, J. , Marcy, T. , Kuehn, S. and Leone, S. (2000), The Direct Production of CO(v=1-9) in the Reaction of O (P-3) With the Ethyl Radical, Journal of Chemical Physics (Accessed June 1, 2024)