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PUBLICATIONS

Diels-Alder Cycloaddition Polymerization for Porous Poly-Phenylenes with Exceptional Gas Uptake Properties

Published

Author(s)

Timur Ashirov, Patrick Fritz, Taner N. Yildirim, Ali Coskun

Abstract

We report the synthesis of two-dimensional and three-dimensional porous polyphenylenes (2D/3D-pPPs) via the Diels–Alder cycloaddition polymerization reaction. The resulting 2D and 3D-pPPs showed surface areas up to 1553 m2 g-1, pore volumes of 1.45 cm3 g-1 and very high H2 uptake capacities of 7.4 and 7.1 wt% at 77 K, respectively, along with a competitive high-pressure CO2 and CH4 uptake performance.
Citation
Chemical Communications
Volume
60
Issue
19
Pub Type
Journals
Materials

Citation

Ashirov, T. , Fritz, P. , Yildirim, T. and Coskun, A. (2024), Diels-Alder Cycloaddition Polymerization for Porous Poly-Phenylenes with Exceptional Gas Uptake Properties, Chemical Communications (Accessed December 12, 2024)

Issues

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Created March 7, 2024, Updated October 30, 2024