Compressive Strengthening of Sapphire by Neutron Irradiation

Published

May 9, 2001

Author(s)

T M. Regan, D C. Harris, R M. Stroud, J R. White, D W. Blodgett, K C. Baldwin, J A. Miragliotta, M E. Thomas, M J. Linevsky, J W. Giles, T A. Kennedy, M Fatemi, David R. Black

Abstract

Neutron irradiation of sapphire with 1 1022(=1 MeV)/m2 increases the c-axis compressive strength by a factor of 3 at 600 C. The mechanism of strength enhancement is the retardation of r-plane twin propagation by radiation-induced defects. 10B and Cd shielding was employed during irradiation to filter out thermal neutrons (= 1 eV), thereby reducing residual radioactivity in the sapphire to background levels in a month. Yellow-brown irradiated sapphire is nearly decolorized to pale yellow by annealing at 600 C with no loss of mechanical strength. Annealing at sufficiently high temperature (such as 1200 C for 24 h) reduces the compressive strength back to its baseline value. Neutron irradiation decreases the flexure strength of sapphire at 600 C by 0%-20% in some experiments. However, the c-plane ring-on-ring flexure strength at 600 C is doubled by irradiation. Elastic constants of irradiated sapphire are only slightly changed by irradiation. Infrared absorption and emission and thermal conductivity of sapphire are not affected by irradiation at the neutron fluence used in this study. Defects that might be correlated with strengthening were characterized by electron paramagnetic resonance spectroscopy. Color centers observed in the ultraviolet absorption spectrum were not clearly correlated with mechanical response. No radiation-induced changes could be detected by x-ray topography or x-ray diffraction.

Proceedings Title

Proceedings of Window and Dome Technologies and Materials VII

Volume

4375

Conference Dates

April 16-20, 2001

Conference Location

Undefined

Conference Title

SPIE Meeting

Pub Type

Conferences

Keywords

neutron irradiation, sapphire, strength

Citation

Regan, T. , Harris, D. , Stroud, R. , White, J. , Blodgett, D. , Baldwin, K. , Miragliotta, J. , Thomas, M. , Linevsky, M. , Giles, J. , Kennedy, T. , Fatemi, M. and Black, D. (2001), Compressive Strengthening of Sapphire by Neutron Irradiation, Proceedings of Window and Dome Technologies and Materials VII, Undefined (Accessed April 23, 2024)