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Chiral Index Dependence of the G+ and G- RamanModes in Semiconducting Carbon Nanotubes



Ming Zheng, Xiaomin X. Tu, Hagen Telg, Stephen K. Doorn, Juan Duque


Raman spectroscopy on the radial breathing mode is a common tool to determine the diameter d or chiral indices (n;m) of single walled carbon nanotubes. In this work we presentan alternative technique to determine d and (n;m) based on the high-energy G mode. From resonant Raman scattering experiments on 14 highly purified single chirality (n;m) samples we obtain the diameter, chiral angle and family dependence of the G and G+ peak position. Considering theoretical predictions we discuss the origin of these dependences with respect to rehybridization of the carbon orbitals, confinement, and electron-electron interactions. The relative Raman intensities of the two peaks have a systematic chiral-angle dependence in agreement with theories considering the symmetry of nanotubes and the associated phonons.
ACS Nano


carbon nanotubes, raman spectroscopy


Zheng, M. , Tu, X. , Telg, H. , Doorn, S. and Duque, J. (2012), Chiral Index Dependence of the G+ and G- RamanModes in Semiconducting Carbon Nanotubes, ACS Nano (Accessed June 3, 2023)
Created January 24, 2012, Updated January 19, 2023