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Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework
Published
Author(s)
Tomce Runcevski, Matthew T. Kapelewski, Rodolfo M. Torres-Gavosto, Jacob Daniel Tarver, Craig Brown, Jeffrey R. Long
Abstract
One strategy to markedly increase the gas storage capacity of metal-organic frameworks, is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single mental site within a framework can support the terminal coordination of two gas molecules - specifically hydrogen, methane, or carbon dioxide.
Runcevski, T.
, Kapelewski, M.
, Torres-Gavosto, R.
, Tarver, J.
, Brown, C.
and Long, J.
(2016),
Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=920725
(Accessed October 13, 2025)