Lagalante, A.
, Abdulagatov, I.
and Bruno, T.
(2002),
Kamlet-Taft Thermosolvatochromic Parameters of Hydrofluorethers and Hydrofluoroether Azeotropic Mixtures, Journal of Chemical and Engineering Data (Accessed April 27, 2026)
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Kamlet-Taft Thermosolvatochromic Parameters of Hydrofluorethers and Hydrofluoroether Azeotropic Mixtures
Published
Author(s)
, I M. Abdulagatov,
Abstract
The electronic transition maxima of three solvatochromic probes were measured at temperatures between (-13.5 and 17 C) in five liquid hydrofluoroether (HFE) solvents. The electronic transition maxima were used to calculate thermosolvatochromic Kamlet-Taft parameters. The solubility of naphthalene and benzoic acid were measured in the HFE solvents and a liner solvation energy relationship (LSER) was calculated to model the solubility data using the measured Kamlet-Taft Thermosolvatochromic parameters. Differences between the Kamlet-Taft values of the pure hydrofluoroethers and azeotropic mixtures of the hydrofluoroethers are discussed as well as the LSER results.Citation
Journal of Chemical and Engineering Data
Volume
47
Issue
No. 1
Pub Type
Journals
Keywords
hydrofluoroethers, hydrogen-bonding, kamlet-Taft parameters, solubility, solvents
Citation
Issues
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Created February 1, 2002, Updated February 17, 2017