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PUBLICATIONS

5f-Electron Excitation Energies and the Coulomb Term, U, in the Light Actinide Metals

Published

Author(s)

J F. Herbst, R E. Watson

Abstract

Relativistic Hartree-Fock-Wigner-Seitz band calculations have been performed for the actinide metals Ac through Am in order to estimate 5f excitation energies. Our calculations predict that the tetravalent state (i.e., four s-d conduction electrons) is favored for the lighter elements with a crossover to a trivalent ground state occurring near uranium. We find the Coulomb energy, U, for 5f electron hopping to increase from 2-3 eV at Th to 4-5 eV at Am.
Citation
Physical Review B (Condensed Matter and Materials Physics)
Volume
34
Issue
22
Pub Type
Journals
Condensed matter

Citation

Herbst, J. and Watson, R. (1975), 5f-Electron Excitation Energies and the Coulomb Term, U, in the Light Actinide Metals, Physical Review B (Condensed Matter and Materials Physics) (Accessed October 15, 2025)

Issues

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Created June 1, 1975, Updated October 12, 2021
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