Ashirov, T.
, Fritz, P.
, Yildirim, T.
and Coskun, A.
(2024),
Diels-Alder Cycloaddition Polymerization for Porous Poly-Phenylenes with Exceptional Gas Uptake Properties, Chemical Communications (Accessed April 25, 2026)
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Diels-Alder Cycloaddition Polymerization for Porous Poly-Phenylenes with Exceptional Gas Uptake Properties
Published
Author(s)
Timur Ashirov, Patrick Fritz, , Ali Coskun
Abstract
We report the synthesis of two-dimensional and three-dimensional porous polyphenylenes (2D/3D-pPPs) via the Diels–Alder cycloaddition polymerization reaction. The resulting 2D and 3D-pPPs showed surface areas up to 1553 m2 g-1, pore volumes of 1.45 cm3 g-1 and very high H2 uptake capacities of 7.4 and 7.1 wt% at 77 K, respectively, along with a competitive high-pressure CO2 and CH4 uptake performance.Citation
Chemical Communications
Volume
60
Issue
19
Pub Type
Journals
Citation
Issues
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Created March 7, 2024, Updated October 30, 2024