Brubaker, Z.
, Xiao, Y.
, Chow, P.
, Kenney-Benson, C.
, Smith, J.
, Cynn, H.
, Reynolds, C.
, Butch, N.
, Zieve, R.
and Jeffries, J.
(2020),
Valence Instability Across the Magnetostructural Transition in USb<sub>2</sub>, Physical Review B, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=928068
(Accessed October 16, 2025)
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Valence Instability Across the Magnetostructural Transition in USb2
Published
Author(s)
Z. E. Brubaker, Y. Xiao, P. Chow, C. Kenney-Benson, J. S. Smith, H. Cynn, C. Reynolds, , R. J. Zieve, J. R. Jeffries
Abstract
We have performed pressure dependent X-ray diffraction and resonant X-ray emission spectroscopy experiments on USb2 to further characterize the AFM-FM transition occuring near 8 GPa. We have found the magnetic transition coincides with a tetragonal to orthorhombic transition resulting in a 17% volume collapse as well as a transient f-occupation enhancement. With increasing atomic size, the UX2 structure shows a decreasing bulk modulus and transition pressure, and an increasing volume collapse at the structural transition. Except for an enhancement across the transition region, the f-occupancy decreases steadily from 1.96 to 1.75.Citation
Physical Review B
Volume
101
Issue
8
Pub Type
Journals
Download Paper
Keywords
X-ray absorption spectroscopy, valence, antiferromagnet
Citation
Issues
If you have any questions about this publication or are having problems accessing it, please contact [email protected].
Created February 13, 2020, Updated October 12, 2021