Skip to main content
U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

X-ray Powder Diffraction Reference Patterns for Bi1-xPbxOCuSe



Winnie K. Wong-Ng, Yonggao Yan, James A. Kaduk, Xinfeng Tang


The structures and powder X-ray reference diffraction patterns of the ‘natural superlattice’ series Bi1-xPbxOCuSe (x=0, 0.02, 0.04, 0.06, 0.08 and 0.1) have been investigated. As the ionic radius of Pb2+ is greater than that of Bi3+, the unit cell volume of Bi1-xPbxOCuSe increases progressively from x=0 to x=0.1, namely, from 137.868(5) Å3 to 139.172(11) Å3, as expected. The structure of Bi1-xPbxOCuSe is built from [Bi2(1-x)Pb2xO2]2(1-x)+ layers normal to the c-axis alternating with [Cu2Se2]2(1-x]- fluorite-like layers. Pb substitution in the Bi site of Bi1-xPbxOCuSe leads to the weakening of the bonding between the [Bi2(1-x)Pb2xO2]2(1-x)+ and the [Cu2Se2]2(1-x]- layers. Powder patterns of Bi1-xPbxOCuSe were submitted to be included in the Powder Diffraction File (PDF).
Powder Diffraction


Thermoelectric material, Bi1-xPbxOCuSe, powder X-ray reference patterns, crystal structure.


Wong-Ng, W. , Yan, Y. , Kaduk, J. and Tang, X. (2016), X-ray Powder Diffraction Reference Patterns for Bi1-xPbxOCuSe, Powder Diffraction, [online], (Accessed April 14, 2024)
Created September 16, 2016, Updated November 10, 2018