U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

PUBLICATIONS

Surface Oxygen Chemistry of a Gas Sensing Material: SnO2(101)

Published

Author(s)

M Batzill, K Katsiev, Anne M. Chaka, A C. Diebold

Abstract

Experimental techniques and density functional theory have been employed to identify the surface composition and structure of SnO2(101). The stoichiometric Sn4+O22- surface is only stable at high oxygen chemical potential. For lower oxidizing potential of the gas phase a Sn2+O2- bulk termination is favored. These two surfaces interconvert without reconstruction by occupying and vacating bridging oxygen sites. This variability of the surface composition is possible because of the dual valency of Sn and is fundamental for the application of this material in gas sensing devices.
Citation
Europhysics Letters
Volume
65 No. 1
Pub Type
Journals

Keywords

Ab initio, DFT, gas sensors, leed, STM, surface science, theory tin oxide

Citation

Batzill, M. , Katsiev, K. , Chaka, A. and Diebold, A. (2004), Surface Oxygen Chemistry of a Gas Sensing Material: SnO<sub>2</sub>(101), Europhysics Letters (Accessed April 22, 2025)

Issues

If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.

Created December 31, 2003, Updated October 12, 2021