Structure and Spectroscopy of Hydrogen Adsorbed in a Nickel Metal-Organic Framework
Craig M. Brown, Anibal Javier Ramirez-Cuesta, Jae-Hyuk Her, Paul S. Wheatley, Russell E. Morris
The structure of Ni2(dobdc) (dobdc4- = 2,5- dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in-situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogues and the Ni2+ variant shows the shortest deuterium-metal distance in the M2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.
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Structure and Spectroscopy of Hydrogen Adsorbed in a Nickel Metal-Organic Framework, Chemical Physics, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=914364
(Accessed December 4, 2023)