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Chemistry

Chemical thermodynamics & chemical properties

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Displaying 326 - 350 of 524

Photochemical Properties of Some Cl-Containing Halogenated Alkanes

May 31, 2013
Author(s)
Vladimir L. Orkin, Victor Khamaganov, E. E. Kasimovskaya, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially halogenated alkanes, CHCl3 (kMC), CHFClCFCl2 (k122a), and CH2CFCl2 (k132c), were measured using a discharge flow – electron paramagnetic resonance technique over the temperature

Thermal Decomposition Kinetics of 1,3,5-Triisopropylcyclohexane

May 29, 2013
Author(s)
Raina V. Gough, Jason A. Widegren, Thomas J. Bruno
Recent surrogate diesel fuel mixture development identified the need for a multiply-substituted, low cetane number, high molecular mass monocycloalkane component. On the basis of a thermophysical property evaluation and prediction, 1,3,5

Experimental investigation of Low-pressure refrigerant mixtures for Micro Cryogenic Coolers

February 4, 2013
Author(s)
Ryan J. Lewis, Yunda Wang, Peter E. Bradley, Marcia L. Huber, Ray Radebaugh, Y. C. Lee
Micro Cryogenic Coolers (MCCs) can achieve very small sizes and high efficiencies when operating with a refrigerant mixture, but micro-scale compressors have a limited pressure output. Four refrigerant mixtures were designed to operate between 0.4 MPa and

ThermoData Engine (TDE): Software Implementation of the Dynamic Data Evaluation Concept. 8. Properties of Material Streams and Solvent Design

December 3, 2012
Author(s)
Vladimir Diky, Robert D. Chirico, Chris D. Muzny, Andrei F. Kazakov, Kenneth G. Kroenlein, Joe W. Magee, Ilmutdin M. Abdulagatov, Carlos A. Diaz-Tovar, Jeong W. Kang, Rafiqul Gani, Michael D. Frenkel
ThermoData Engine (TDE) is the first full-scale software implementation of the dynamic data evaluation concept, as reported in this journal. The present paper describes the first application of this concept to the evaluation of thermophysical properties for

Development of a 4K Regenerator and Pulse Tube Test Facility

October 10, 2012
Author(s)
Michael A. Lewis, Peter E. Bradley, Ryan P. Taylor, Ray Radebaugh
Recent advances in superconducting electronic systems are requiring larger envelopes for cooling power, efficiency, and operational environments from commercial based cryogenic cooling systems. One such system targeted at meeting these requirements is the

Thermal Decomposition of 1-Pentyl Radicals at High Pressures and Temperatures

September 27, 2012
Author(s)
Andrea Comandini, Iftikhar A. Awan, Jeffrey A. Manion
Complementary shock-tube studies at the National Institute of Standards and Technology (NIST) and the University of Illinois at Chicago (UIC) have been used to examine the decomposition reactions of the 1-pentyl radical at temperatures of 833 K to 1130 K

The Decomposition of 2-Pentyl and 3-Pentyl Radicals

July 15, 2012
Author(s)
Jeffrey A. Manion, Iftikhar A. Awan
The isomerization and decomposition reactions of 2-pentyl and 3-pentyl radicals have been studied in a single-pulse shock tube over a temperature range of 973 K to 1121 K and pressures of 120 kPa to 800 kPa. The results represent the first direct study of

Verification of the Back-EMF Method for Piston Velocity Measurements

July 10, 2012
Author(s)
Ray Radebaugh, Michael A. Lewis, Peter E. Bradley
Linear compressors are used to drive pulse tube or Stirling cryocoolers, and they can be used as expanders in place of inertance tubes when inertance tubes cannot provide sufficient phase shifts between flow and pressure. Commercial linear compressors
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