Reference materials for phase equilibrium studies. 2. Solid–liquid equilibria (IUPAC Technical Report)

Published

January 11, 2023

Author(s)

Ala Bazyleva, William E. Acree, Vladimir Diky, Glenn T. Hefter, Johan Jacquemin, M. Clara F. Magalhães, Joe W. Magee, Kirk Nordstrom, John O'Connell, James D. Olson, Ilya Polishuk, Kurt A. G. Schmidt, John M. Shaw, J. P. Martin Trusler, Ronald D. Weir

Abstract

This article is the second of three projected IUPAC Technical Reports on reference materials for phase equilibrium studies. The goal of this project was to select reference systems with critically evaluated property values for the verification of instruments and techniques used in phase equilibrium studies of mixtures. This report proposes seven systems for solid–liquid equilibrium studies, covering the four most common categories of binary mixtures: aqueous systems with organic solutes, aqueous systems with inorganic solutes, non-aqueous systems, and systems with low solubility. For each system, the available literature sources, accepted data, smoothing equations, and estimated uncertainties are given.

Citation

Pure and Applied Chemistry

Volume

94

Issue

11-12

Pub Type

Journals

Download Paper

https://doi.org/10.1515/pac-2021-1002

Local Download

Keywords

Experimental method corroboration, phase equilibrium, reference materials, solid–liquid equilibrium, solubility

Citation

Bazyleva, A. , Acree, W. , Diky, V. , Hefter, G. , Jacquemin, J. , Magalhães, M. , Magee, J. , Nordstrom, K. , O'Connell, J. , Olson, J. , Polishuk, I. , Schmidt, K. , Shaw, J. , Trusler, J. and Weir, R. (2023), Reference materials for phase equilibrium studies. 2. Solid–liquid equilibria (IUPAC Technical Report), Pure and Applied Chemistry, [online], https://doi.org/10.1515/pac-2021-1002, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=933262 (Accessed April 19, 2024)