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Rectangular Scale-Similar Etch Pits in Monocrystalline Diamond



Craig D. McGray, Richard A. Allen, Marc J. Cangemi, Jon C. Geist


Etching of monocrystalline diamond in oxygen and water vapor at 1100° C through small pores in a silicon nitride film produced smooth-walled rectangular cavities. The cavities were imaged by electron microscope and measured by interferometric microscopy. The observed cavities ranged in size from approximately 1 µm up to 72 µm wide, in each case exhibiting smooth, vertical sidewalls, a flat bottom, and a depth equal to half its width. Cavity boundaries were determined to lie along slow-etching (100) crystallographic planes, suggesting the possibility of a powerful class of techniques for high-aspect-ratio bulk micromachining of diamond.
Diamond and Related Materials


diamond, anisotropic etching, crystallographic etching, oxidation, micromachining, MEMS, nanofabrication


McGray, C. , Allen, R. , Cangemi, M. and Geist, J. (2011), Rectangular Scale-Similar Etch Pits in Monocrystalline Diamond, Diamond and Related Materials, [online], (Accessed June 23, 2024)


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Created September 15, 2011, Updated February 19, 2017