Duan, X.
, Yu, J.
, Cai, J.
, He, Y.
, Wu, C.
, Zhou, W.
, Yildirim, T.
, Zhang, Z.
, Xiang, S.
, O'Keeffe, M.
, Chen, B.
and Qian, G.
(2013),
A Microporous Metal-Organic Framework of a Rare sty Topology for High CH<sub>4</sub> Storage at Room Temperature, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=913286
(Accessed October 11, 2025)
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A Microporous Metal-Organic Framework of a Rare sty Topology for High CH4 Storage at Room Temperature
Published
Author(s)
Xing Duan, Jiancan Yu, Jianfeng Cai, Yabing He, Chuande Wu, , , Zhangjing Zhang, Shengchang Xiang, Michael O'Keeffe, Banglin Chen, Guodong Qian
Abstract
A rare sty type microporous metal-organic framework Cu2(FDDI) (ZJU-25; H4FDDI = tetramethyl 5,5'-(9H-fluorene-2,7-diyl)diisophthalate acid) was solvothermally synthesized and structurally characterized. With open metal sites and suitable pore space for their interactions with methane molecules, ZJU-25a exhibits absolute methane storage of 180 cm3(STP)/cm3 at room temperature and 35 bar, enabling it to be one of the very few porous MOFs whose methane storage capacities have met and/or approached the DOE target of 180 cm3(STP)/cm3 for material-based methane storage.Citation
Chemical Communications
Volume
49
Pub Type
Journals
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Keywords
metal-Organic Framework, methane storage
Citation
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Created February 21, 2013, Updated October 12, 2021