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Metal Hydrazinoborane LiN2H3BH3 and LiN2H3BH3𔅖N2H4BH3: Crystal Structures and High-Extent Dehydrogenation

Published

Author(s)

Hui Wu, Wei Zhou, Frederick E. Pinkerton, Terrence J. Udovic, Taner Yildirim, John J. Rush

Abstract

The first example of metal hydrazinoborane, LiN2H3BH3, and its hydrazine borane adduct LiN2H3BH32N2H4BH3 were synthezised with their crystal structures successfully determined. The metal hydrazinoboranes exhibit dramatically improved dehydrogenation over the pristine hydrazine borane (N2H4BH3) with nearly complete dehydrogenation at mild temerature range (50-225°C) and high purity of H2 release.
Citation
Energy & Environmental Science
Volume
5

Keywords

hydrogen storage, crystal structure, dehydrogenation

Citation

Wu, H. , Zhou, W. , , F. , Udovic, T. , Yildirim, T. and Kasianowicz, J. (2012), Metal Hydrazinoborane LiN<sub>2</sub>H<sub>3</sub>BH<sub>3</sub> and LiN<sub>2</sub>H<sub>3</sub>BH<sub>3</sub>&#82262N<sub>2</sub>H<sub>4</sub>BH<sub>3</sub>: Crystal Structures and High-Extent Dehydrogenation, Energy & Environmental Science, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=911146 (Accessed July 23, 2024)

Issues

If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.

Created June 1, 2012, Updated February 19, 2017