Skip to main content

NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.

Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.

U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Magic Wavelengths for the np - ns Transitions in Alkali-Metal Atoms

Published

Author(s)

B Arora, M S. Safronova, Charles W. Clark

Abstract

Extensive calculations of the electric-dipole matrix elements in alkali-metal atoms are conducted using the relativistic all-order method. This approach is a linearized version of the coupled-cluster method, which sums infinite sets of many-body perturbation theory terms. All allowed transitions between the lowest ns, np1/2, np3/2 states and a large number of excited states are considered in these calculations and their accuracy is evaluated. The resulting electric-dipole matrix elements are used for the high-precision calculation of frequency-dependent polarizabilities of the excited states of alkali-metal atoms. We find magic wavelengths in alkali-metal atoms for which the ns and np1/2 and np3/2 atomic levels have the same ac Stark shifts, which facilitates state-insensitive opticalcooling and trapping.
Citation
Physical Review A (Atomic, Molecular and Optical Physics)
Volume
76
Issue
052509

Keywords

atom trap, atomic clock, atomic structure, cesium, laser cooling, polarizability, potassium, rubidium, sodium

Citation

Arora, B. , Safronova, M. and Clark, C. (2007), Magic Wavelengths for the np - ns Transitions in Alkali-Metal Atoms, Physical Review A (Atomic, Molecular and Optical Physics), [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=840266 (Accessed October 14, 2025)

Issues

If you have any questions about this publication or are having problems accessing it, please contact [email protected].

Created November 14, 2007, Updated October 12, 2021
Was this page helpful?