Rosado-Reyes, C.
, Manion, J.
and Tsang, W.
(2010),
Kinetics of the Thermal Reaction of H Atoms with Propyne, Journal of Physical Chemistry
(Accessed July 2, 2025)
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Kinetics of the Thermal Reaction of H Atoms with Propyne
Published
Author(s)
, ,
Abstract
The reaction of hydrogen atoms with propyne(CH≡CCH3) has been investigated in a heated single pulse shock tube at temperatures of 870-1145K and pressures of 2-9 bar. Stable products from various reaction channels (terminal and non-terminal H addition, and by inference H abstraction) have been identified and quantified by gas chromatography and mass spectrometry. The rate constant for the channel involving the displacement of methyl radical from propyne (non-terminal H addition) was determined relative to the methyl displacement from 1,3,5-trimethylbenzene (1,3,5-TMB), with k (H + 1,3,5-TMB → m-Xylene + CH3) = 6.70 ¿ 1013 exp(-3255/T) cm3/moles, k (H + Propyne → CH≡CH + CH3) = 6.361013 exp(-2285/T) cm3/molesec (see document for complete abstract)Citation
Journal of Physical Chemistry
Pub Type
Journals
Keywords
propyne, propargyl, H-atom, single pulse shock tube, displacement, abstraction, addition, high temperatures, pyrolysis
Citation
Issues
If you have any questions about this publication or are having problems accessing it, please contact [email protected].
Created April 15, 2010, Updated February 19, 2017