Babushok, V.
and Linteris, G.
(2018),
Kinetic Mechanism of 2,3,3,3-Tetrafluoropropene (HFO-1234yf) Combustion, Journal of Fluorine Chemistry, [online], https://doi.org/10.1016/j.jfluchem.2017.07.005 (Accessed May 8, 2026)
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Kinetic Mechanism of 2,3,3,3-Tetrafluoropropene (HFO-1234yf) Combustion
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Abstract
A kinetic model for 2,3,3,3-tetrafluoropropene (HFO-1234yf) high temperature oxidation and combustion is proposed. It is combined with the GRI-Mech-3.0 model, with the previously developed model for 2-bromo-3,3,3-trifluoropropene (2-BTP), and with the NIST C1-C2 hydrofluorocarbon model. The model includes 909 reactions and 101 species. Combustion equilibrium calculations indicate a maximum combustion temperature of 2076 K for an HFO-1234yf volume fraction of 0.083 in air for standard conditions (298 K, 0.101 MPa). Calculations of flame propagation in mixtures of 2,3,3,3-tetrafluoropropene with oxygen enriched air are performed and results are compared with experimental data.Citation
Journal of Fluorine Chemistry
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Journals
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Keywords
R-1234yf, Refrigerant flammability, Burning velocity, Low ODP/GWP refrigerants, kinetic model
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Created July 16, 2018, Updated November 10, 2018