NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.
Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.
An official website of the United States government
Here’s how you know
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Intensity Effects in Ultracold Photoassociation Line Shapes
Published
Author(s)
A Simoni, Paul S. Julienne, Eite Tiesinga, Carl J. Williams
Abstract
We derive ultracold atom-atom photoassociation line shapes valid for intense light fields and investigate laser power effects in sodium and rubidium photoassociation to the purely long range 0g- symmetry state. We consider intensities up to few hundreds W/cm2, a strongly saturating intensity for typical transitions of experimental interest. For these intensities the 0g- rotational spectrum is still well resolved; however, it is essential to couple the photoassociation resonance to both s- and d-wave ground state channels. A low energy d-wave shape resonance can have a profound effect on the line shape. Understanding the line shape is essential for precision spectroscopic analysis and could improve the extraction of ground-state scattering properties such as scattering lengths.
Citation
Physical Review A (Atomic, Molecular and Optical Physics)
Simoni, A.
, Julienne, P.
, Tiesinga, E.
and Williams, C.
(2002),
Intensity Effects in Ultracold Photoassociation Line Shapes, Physical Review A (Atomic, Molecular and Optical Physics)
(Accessed October 12, 2025)