Skip to main content

NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.

Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.

U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Intensity Effects in Ultracold Photoassociation Line Shapes

Published

Author(s)

A Simoni, Paul S. Julienne, Eite Tiesinga, Carl J. Williams

Abstract

We derive ultracold atom-atom photoassociation line shapes valid for intense light fields and investigate laser power effects in sodium and rubidium photoassociation to the purely long range 0g- symmetry state. We consider intensities up to few hundreds W/cm2, a strongly saturating intensity for typical transitions of experimental interest. For these intensities the 0g- rotational spectrum is still well resolved; however, it is essential to couple the photoassociation resonance to both s- and d-wave ground state channels. A low energy d-wave shape resonance can have a profound effect on the line shape. Understanding the line shape is essential for precision spectroscopic analysis and could improve the extraction of ground-state scattering properties such as scattering lengths.
Citation
Physical Review A (Atomic, Molecular and Optical Physics)
Volume
66
Issue
No. 6

Keywords

photoassociation spectroscopy, rubidium dimer, sodium dimer, strong light fields, ultra-cold collisions

Citation

Simoni, A. , Julienne, P. , Tiesinga, E. and Williams, C. (2002), Intensity Effects in Ultracold Photoassociation Line Shapes, Physical Review A (Atomic, Molecular and Optical Physics) (Accessed October 12, 2025)

Issues

If you have any questions about this publication or are having problems accessing it, please contact [email protected].

Created November 30, 2002, Updated October 12, 2021
Was this page helpful?