Freezing of the Local Dynamics in the Relaxor Ferroelectric [Pb(Zn1⁄2Nb2/3})O3]0.955[PbTiOd3^]^d0.045

Published

October 5, 2012

Author(s)

Zhijun Xu, Jinsheng Wen, E. Mamontov, Chris Stock, Peter M. Gehring, Guangyong Xu

Abstract

We report measurements of the neutron diffuse scattering in a single crystal of the relaxor ferroelectric material 95.5%Pb(Zn1/3Nb2/3)O3-4.5%PbTiO3 (PZN-4.5%PT). We show that the diffuse scattering at high temperatures has a quasielastic component with energy width > 0.1 meV. On cooling the total diffuse scattering intensity increases, but the intensity and the energy width of the quasielastic component gradually diminish. At 50K the diffuse scattering is completely static (i. e. the energy width lies within the limits of our instrumental resolution). This suggests that the dynamics of the short-range correlated atomic displacements associated with the diffuse scattering freeze at low temperature. We find that this depends on the wave vector q as the quasielastic diffuse scattering intensities associated with <001> (T1-type) and <110> (T2-type) atomic displacements vary differently with temperature and electric field.

Citation

Physical Review B

Volume

86

Issue

14

Pub Type

Journals

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Keywords

Relaxors, diffuse scattering, polar nanoregions, PZN-xPT, relaxational dynamics, neutron scattering

Citation

Xu, Z. , Wen, J. , Mamontov, E. , Stock, C. , Gehring, P. and Xu, G. (2012), Freezing of the Local Dynamics in the Relaxor Ferroelectric [Pb(Zn1&#8260;2Nb{2/3})O₃]_0.955[PbTiOd3^]^d0.045, Physical Review B, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=911202 (Accessed April 19, 2024)