Kumari, H.
, Armitage, S.
, Kline, S.
, Damodaran, K.
, Kennedy, S.
, Atwood, J.
and Steed, J.
(2015),
Fluorous 'Ponytails' Lead to Strong Gelators Showing Thermally Induced Structure Evolution, Soft Matter, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=919074
(Accessed May 5, 2024)
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Fluorous 'Ponytails' Lead to Strong Gelators Showing Thermally Induced Structure Evolution
Published
Author(s)
Harshita Kumari, Sarah E. Armitage, , Krishna K. Damodaran, Stuart R. Kennedy, Jerry L. Atwood, Jonathan W. Steed
Abstract
Appending perfluoroalkyl substituents to bis(urea) gelators results in significantly decreased interchain interactions with markedly thinner fibres and hence more cross-linked and more transparent gels with potential applications in the crystallisation of fluorinated pharmaceuticals. Gel structure has been probed be detailed SANS measurements which indicate a surprise structure evolution on thermal cycling, not seen for hydrocarbon analogues. The SANS data are complemented by the single crystal X-ray structure of one fluorinated gelator.Citation
Soft Matter
Volume
11
Issue
43
Pub Type
Journals
Download Paper
Keywords
gelators, small-angle scattering, fluorinated materials, x-ray crystallography, thermoreversible, microscopy
Citation
Created September 2, 2015, Updated October 12, 2021