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Anthony P. Hamins, G. Gmurczyk, William L. Grosshandler, R. G. Rehwoldt, I Vazquez, Thomas G. Cleary, Cary Presser, K Seshadri
Abstract
A flame will be extinguished when the time required for the chain reaction which sustains combustion exceeds the time it takes to replenish the necessary heat and reactants. A characteristic time for reaction can be estimated from the inverse of a global kinetic rate coefficient expressed in Arrhenius form as [equation] where B is a molecular collision frequency factor, Eo is a global activation energy, R is the ideal gas constant, and T is the gas temperature. Assuming reactant species and heat are transported at about the same rate (i.e., unity Lewis number), a characteristic time for replenishing both can be estimated from a convective flow velocity and a length scale by [equation].
Hamins, A.
, Gmurczyk, G.
, Grosshandler, W.
, Rehwoldt, R.
, Vazquez, I.
, Cleary, T.
, Presser, C.
and Seshadri, K.
(1994),
Flame Suppression Effectiveness (NIST SP 861), Special Publication (NIST SP), National Institute of Standards and Technology, Gaithersburg, MD, [online], https://doi.org/10.6028/NIST.SP.861
(Accessed October 1, 2025)