NOTICE: Due to a lapse in annual appropriations, most of this website is not being updated. Learn more.
Form submissions will still be accepted but will not receive responses at this time. Sections of this site for programs using non-appropriated funds (such as NVLAP) or those that are excepted from the shutdown (such as CHIPS and NVD) will continue to be updated.
An official website of the United States government
Here’s how you know
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
First Observation of the Pure Long-Range 1u State of an Alkali Dimer by Photoassociative spectroscopy
Published
Author(s)
X Wang, H Wang, P L. Gould, W C. Stwalley, Eite Tiesinga, Paul S. Julienne
Abstract
The pure long-range 1u state of an alkali dimer is observed for the first time in 39K2 using photoassociative spectroscopy of ultracold atoms. High-resolution spectra for vibrational levels v = O to 7 are recorded by resonance-enhanced two-photon ionization. Strong rotation-hyperfine couplings are observed. Major molecular constants and a hyperfine structure analysis are presented. This 1u state is useful as a novel ungerade Franck-Condon window at large internuclear distance for studies of highly-excited long-range interactions.
Citation
Physical Review A (Atomic, Molecular and Optical Physics)
Wang, X.
, Wang, H.
, Gould, P.
, Stwalley, W.
, Tiesinga, E.
and Julienne, P.
(1998),
First Observation of the Pure Long-Range 1<sub>u</sub> State of an Alkali Dimer by Photoassociative spectroscopy, Physical Review A (Atomic, Molecular and Optical Physics)
(Accessed October 11, 2025)