Zhou, C.
, Hobbie, E.
, Bauer, B.
and Han, C.
(1998),
Equilibrium Structure of Hydrogen-Bonded Polymer Blends, Journal of Polymer Science Part B-Polymer Physics, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=851437
(Accessed December 5, 2024)
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Equilibrium Structure of Hydrogen-Bonded Polymer Blends
Published
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Abstract
Deuterium-labeled polystyrene modified by random distributions of the comonomer p-(1,1,1,3,3,3-hexaflouro-2-hydroxyisopropyl)-α-Methyl-styrene [DPS(OH)] has been blended with poly (butyl methacrylate) (PBMA) and studied with small-angle neutron scattering (SANS). Miscibility is induced via hydrogen bonding between the DPS (OH) hydroxyl group and PBMA carbonyl groups. The data suggest that the nature of the miscible-phase structure in these blends differs from that of the usual homopolymer blends at small scattering angles, which we attribute to the short-range site specific nature of the hydrogen bond interaction.Citation
Journal of Polymer Science Part B-Polymer Physics
Volume
36
Issue
No. 15
Pub Type
Journals
Download Paper
Keywords
hydrogen bond, polymer blend, SANS
Citation
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Created November 1, 1998, Updated February 17, 2017