Howe, P.
, Fahr, A.
and Laufer, A.
(2004),
Effect of Water Vapor on the Combination and Disproportionation of Ethyl Radicals in the Gas Phase, Journal of Physical Chemistry A
(Accessed June 7, 2023)
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Effect of Water Vapor on the Combination and Disproportionation of Ethyl Radicals in the Gas Phase
Published
Author(s)
P -. Howe, ,
Abstract
The role of H2O vapor on the disproportionation/combination ratio (kd/kc) of C2H5 radical reactions in the gas phase has been investigated experimentally and compared to that observed previously in aqueous solution. At added water pressures of 20 mbar (15 Torr), kd/kc ratio remains unchanged from that observed in its absence. The relationship of the invariant ratio to bonding and solvation phenomena are discussed.Citation
Journal of Physical Chemistry A
Volume
108
Issue
No. 10
Pub Type
Journals
Keywords
combination, disproportionation, effects, ethyl radicals, vapor, water
Citation
Created February 29, 2004, Updated October 12, 2021