Guo, Y.
, Wu, H.
, Zhou, W.
and Yu, X.
(2011),
Dehydrogenation Tuning of Ammine Borohydrides using Double-Metal Cations, Journal of American Chemical Society, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=908059
(Accessed December 3, 2024)
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Dehydrogenation Tuning of Ammine Borohydrides using Double-Metal Cations
Published
Author(s)
Yanhui Guo, , , Xuebin Yu
Abstract
The strategy of using double-cation to tune the temperature and purity of dehydrogenation of ammine borohydrides is reported. The first double-cation ammine borohydride, Li2Al(BH4)5¿6NH3, which forms a novel structure with ordered arrangement of Al(NH3)63+ ammine complexes and Li2(BH4)53- complex anions, is found to release over 10.0 wt.% hydrogen below 120 °C with favorable kinetics and high H-purity (>99%).Citation
Journal of American Chemical Society
Volume
113
Pub Type
Journals
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Citation
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Created March 9, 2011, Updated October 12, 2021