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Dehydrogenation Tuning of Ammine Borohydrides using Double-Metal Cations

Published

Author(s)

Yanhui Guo, Hui Wu, Wei Zhou, Xuebin Yu

Abstract

The strategy of using double-cation to tune the temperature and purity of dehydrogenation of ammine borohydrides is reported. The first double-cation ammine borohydride, Li2Al(BH4)5¿6NH3, which forms a novel structure with ordered arrangement of Al(NH3)63+ ammine complexes and Li2(BH4)53- complex anions, is found to release over 10.0 wt.% hydrogen below 120 °C with favorable kinetics and high H-purity (>99%).
Citation
Journal of American Chemical Society
Volume
113

Citation

Guo, Y. , Wu, H. , Zhou, W. and Yu, X. (2011), Dehydrogenation Tuning of Ammine Borohydrides using Double-Metal Cations, Journal of American Chemical Society, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=908059 (Accessed April 14, 2024)
Created March 9, 2011, Updated October 12, 2021