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Defect-Related Lattice Strain and the Transition Temperature in Ferroelectric Thin Films

Published

Author(s)

Davor Balzar

Abstract

We propose an extension to the phenomenological thermodynamic Landau-Ginzburg-Devonshire theory to include the contribution of inhomogeneous strains caused by lattice defects to the Gibbs free energy. The model yields correction terms for dielectric and ferroelectric quantities as a function of both elastic misfit strain and defect-related strain that can be measured by x-ray diffraction techniques. We compare the correction in Curie-Weiss temperature due to elastic and inhomogeneous strain in pristine, W and Mn 1 % doped Ba0.6Sr0.4TiO3 thin films grown on the LaAlO3 substrate. If the contribution of inhomogeneous strain is included, the agreement with measurements markedly improves.
Citation
Applied Physics Letters

Keywords

curie-weiss temperature, defects, ferroelectrics, strain

Citation

Balzar, D. (2008), Defect-Related Lattice Strain and the Transition Temperature in Ferroelectric Thin Films, Applied Physics Letters (Accessed April 26, 2024)
Created October 16, 2008