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A Broad Perspective on the Dynamics of Highly Confined Polymer Films

Published

Author(s)

Christopher L. Soles, Jack F. Douglas, Wen-Li Wu, H Peng, D W. Gidley

Abstract

The manner in which the dynamics of a polymer are affected by thin film confinement is of technological significance, impacting thin film applications such as lubricants, adhesives, and chemically amplified photoresists. In this manuscript we use specular X-ray reflectivity (SXR), beam positron annihilation lifetime spectroscopy (PALS), and incoherent neutron scattering (INS) to study the influence of thin film confinement on the apparent glass transition temperature Tg and the thermal expansion coefficients of thin polycarbonate (PC) films. Both the SXR and PALS indicate a significant suppression of Tg when the film thickness becomes less than 200 . However, the INS measurements suggest an increase in the apparent Tg below this same length scale. These disparate estimates of the thin film Tg seem to indicate that each technique is sensitive to slightly different aspects of the glass formation process. However, all three agree that thin film confinement results in reduced thermal motion, regardless of the precise temperature that is 'designated' as the thin film Tg.
Citation
MRS Conference
Volume
265(2)

Keywords

dynamics, glasstransition, neutron scattering, positron annihilation, thin films, x-ray reflectivity

Citation

Soles, C. , Douglas, J. , Wu, W. , Peng, H. and Gidley, D. (2002), A Broad Perspective on the Dynamics of Highly Confined Polymer Films, MRS Conference, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=852034 (Accessed April 14, 2024)
Created January 1, 2002, Updated February 17, 2017