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AMS and Microprobe Analysis of Combusted Particles in Ice and Snow

Published

Author(s)

S R. Biegalski, George A. Klouda, R Weissenbok, Lloyd A. Currie, Robert A. Fletcher

Abstract

Ice cores and snow pits of the cryosphere contain particles that detail the history of past atmospheric air compositions. Some of these particles result from combustion processes and have undergone long-range transport to arrive in the Arctic. Recent research has focused on the separation of particulate matter from ice and snow as well as the subsequent analysis of the separated particles for 14C with accelerator mass spectrometry (AMS) and for individual particle compositions with laser microprobe mass analysis (LAMMA). The very low particulate concentrations in Arctic samples make these measurements a challenge. The first task is to separate the particles from the ice core. Two major options exit to accomplish this separation. One option is to melt the ice and then filter the melt water. A second option is to directly sublimate the ice core directly, depositing the particles onto a surface. This work has demonstrated that greater control is obtained through sublimation. A suite of analytical methods has been used for the measurement of the carbon in snow and ice. Total carbon was analyzed with a Carbon/nitrogen/hydrogen (CHN) analyzer. AMS was used for the determination of carbon isotopes. Since source identification of the carbonaceous particles is of primary importance here, the use of LAMMA was incorporated to link individual particle molecular-structural patterns to the the same group of particles that were measured by the other techniques. Prior to this study, neither AMS nor LAMMA had been applied to particles contained in snow. This paper discusses the development and limitations of the methodology required to make these measurements.
Citation
Radiocarbon
Volume
40
Issue
No. 1-2

Keywords

AMS, carbon snow, Greenland, ice, LAMMA, sublimation

Citation

Biegalski, S. , Klouda, G. , Weissenbok, R. , Currie, L. and Fletcher, R. (1998), AMS and Microprobe Analysis of Combusted Particles in Ice and Snow, Radiocarbon (Accessed April 24, 2024)
Created August 1, 1998, Updated February 17, 2017