Accelerated Weathering Parameters for Some Aromatic Engineering Thermoplastics. Part 2: Polycarbonate copolymers, polyarylate and ABS

Published

August 16, 2020

Author(s)

Li Piin Sung, James E. Pickett, Olga Kuvshinnikova, Brett Ermi

Abstract

Understanding the responses of materials to environmental variables is essential for performing meaningful accelerated weathering and service life prediction. Samples of polycarbonate-b-resorcinol polyarylate copolymer (RPA), poly(acrylonitrile-co-butadiene-co-styrene) (SAN) and two polycarbonate copolymers with silicone and aliphatic diacids were exposed in the NIST (National Institutes of Standards and Technology) SPHERE (Simulated Photodegradation via High Energy Radiant Exposure) to determine the effects of ultraviolet (UV) intensity (irradiance), temperature, relative humidity (RH), and UV wavelength on yellowing and gloss loss and compared to other aromatic polymers. All showed proportional response to irradiance (i.e. reciprocity) except ABS, which deviated notably at elevated temperatures. The activation energy for ABS yellowing was higher than other aromatic polymers (31 kJ mol-1  2 kJ mol-1) while RPA had a slightly negative activation energy (-5 kJ mol-1  3 kJ mol-1), reflecting differences in their photodegradation mechanisms. These two polymers also exhibited faster degradation when the RH was  10 % compared to  50 % RH. Wavelength effects varied among the polymers. The results indicate that predictive accelerated weathering should be performed with UV sources that accurately reproduce sunlight, at temperatures as close as possible to use conditions, and with RH > 10 %.

Citation

Polymer Degradation and Stability

Issue

181

Pub Type

Journals

Download Paper

https://doi.org/10.1016/j.polymdegradstab.2020.109

Local Download

Keywords

polycarbonate, resorcinol polyarylate, ABS, weathering, reciprocity, activation energy, humidity

Citation

Sung, L. , Pickett, J. , Kuvshinnikova, O. and Ermi, B. (2020), Accelerated Weathering Parameters for Some Aromatic Engineering Thermoplastics. Part 2: Polycarbonate copolymers, polyarylate and ABS, Polymer Degradation and Stability, [online], https://doi.org/10.1016/j.polymdegradstab.2020.109 (Accessed June 5, 2023)