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Publication Citation: Recommended vapor pressure and thermophysical data for ferrocene

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Author(s): Michal Fulem; Kvetoslav Ruzicka; Marisa A. Rocha; Luis M.N.B.F. Santos; Robert F. Berg;
Title: Recommended vapor pressure and thermophysical data for ferrocene
Published: August 14, 2012
Abstract: Recommended vapor pressure data for ferrocene (CAS Registry Number: 102-54-5) in the temperature range from 242 to 447 K were developed by the simultaneous correlation of critically assessed vapor pressures, heat capacities of the crystalline phase and the ideal gas, and calorimetrically determined enthalpies of sublimation. All of the properties needed for the correlation were newly determined in this work. The value for the enthalpy of sublimation, (298.15 K) = (74.38 ± 0.38) kJ,mol-1, is recommended. Comparisons with literature values are shown for all measured and derived properties.
Citation: Journal of Chemical Thermodynamics
Volume: 57
Pages: pp. 530 - 540
Keywords: ferrocene, heat capacity, ideal gas thermodynamic, recommended vapor pressure, sublimation enthalpy, vapor pressure
Research Areas: Calibrations (Thermodynamic), Chemistry, Thermodynamics, Properties
DOI: http://dx.doi.org/10.1016/j.jct.2012.07.023  (Note: May link to a non-U.S. Government webpage)
PDF version: PDF Document Click here to retrieve PDF version of paper (457KB)