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Publication Citation: Dielectric Spectroscopy Investigation of Relaxation in C60-Polyisoprene Nanocomposites

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Author(s): Yifu Ding; Sebastian Pawlus; Alexei Sokolov; Jack F. Douglas; Alamgir Karim; Christopher L. Soles;
Title: Dielectric Spectroscopy Investigation of Relaxation in C60-Polyisoprene Nanocomposites
Published: March 23, 2009
Abstract: We investigate the influence of adding C60 nanoparticles on the dielectric relaxation spectra of both unentangled and entangled polyisoprene (PIP). Relaxation modes corresponding to both segmental and chain relaxation were analyzed over a broad temperature and frequency range. Regardless of whether the chains were entangled or not, both these relaxation processes slowed down with the addition of C60, reflecting an increase of the nanocomposite glass transition temperature. However, the addition of C60 affects the segmental relaxation much stronger than the large scale chain relaxation, both in terms of the relaxation time and its strength, suggesting that the effect of the nanoparticles on the polymer dynamics is scale dependent. This effect is attributed to a difference in packing frustration at different length scales, a phenomenon that is also relevant to understanding the difference between the temperature dependence of the segmental and chain relaxation processes in neat polymer materials. Further evidence of this scale dependence is indicated by the finding that the secondary or Johari-Goldstein relaxation time of the entangled PIP material decreases with an addition of C60. These observations indicate that C60 has an effect opposite to antiplasticizing additives that slow down the secondary relaxation (stiffening the material) in the glass state, while at the same time reducing the alpha relaxation time associated with cooperative segmental and chain motions. Recent incoherent neutron scattering measurements have indicated that C60 can have a similar effect on high and low frequency relaxation processes of polystyrene.
Citation: Macromolecules
Volume: 42
Pages: pp. 3201 - 3206
Keywords: dielectric spectroscopy, fullerene, antiplasticization, beta relaxtion, glass transition
Research Areas: Polymers, Nanomaterials, Materials Science, Nanotechnology, Characterization, Nanometrology, and Nanoscale Measurements
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