| Author(s): |
William E. Wallace III; |
| Title: |
Reactive MALDI Mass Spectrometry: Application to High Mass Alkanes and Polyethylene |
| Published: |
August 21, 2007 |
| Abstract: |
A molecular solid of fullerene (C60) intercalated with cobalt cyclopentadienyl dicarbonyl (CoCp(CO)2) was shown to be an effective matrix for matrix-assisted laser desorption/ionization mass spectrometry (MALDI) of large alkanes (demonstrated up to C94H190) and polyethylenes that otherwise cannot be produced as intact ions in the gas phase. |
| Citation: |
Chemical Communications |
| Volume: |
2007 |
| Pages: |
pp. 4525 - 4527 |
| Keywords: |
analytical chemistry;molecular mass distribution;organometallic;petroleum;polyolefin;synthetic polymer |
| Research Areas: |
Polymers |
| PDF version: |
 Click here to retrieve PDF version of paper (328KB) |
