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Author: Kirt Page

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1. Interfacial morphology and water transport of proton-conducting polymer membranes in fuel cell
Published: 7/5/2013
Authors: Sangcheol Kim, Joseph A. Dura, Kirt Anthony Page, Christopher L Soles
Abstract: We quantify the interfacial structure and corresponding water transport kinetics in thin films of Nafion using neutron reflectivity (NR) and quartz-crystal microbalance (QCM) by integrating these measurements with in-situ, controlled relative hum ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=913156

2. Capturing nanoscale in network gels by microemulsion polymerization
Published: 12/3/2012
Authors: Kirt Anthony Page, John Texter, Dustin England
Abstract: Difficulties in capturing nanoscale structure by polymerizing microemulsions have persisted with the use of thermal initiation. Bicontinuous microemulsion polymerization with reactive surfactant monomer and cross-linker was done with only a 20% i ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=912333

3. Effect of Confinement on Structure, Water Solubility and Water Transport in Nafion Thin Films
Published: 9/19/2012
Authors: Kirt Anthony Page, Scott Eastman, Shuhui Kang, Christopher L Soles, Brandon W. Rowe
Abstract: Fuel cells based on polymer electrolyte membranes (PEM) show promise as a means of energy conversion for a wide range of applications both in the transportation sector and for stationary power production due to their high charge density and low opera ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=911014

4. An Overview of Polymer Electrolyte Membranes for Fuel Cell Applications
Published: 5/7/2012
Authors: Brandon W. Rowe, Kirt Anthony Page
Abstract: While fuel cells have receive considerable attention over the last 10-20 years, the history of hydrogen fuel cells dates back to 1838. It would take more than a century before polymers would be impletmented as an electrolyte for proton transport (19 ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=909357

5. Inelastic Neutron Scattering on Polymer Electrolytes for Lithium-Ion Batteries
Published: 5/7/2012
Authors: Huagen H. Peng, Madhu Sudan Tyagi, Kirt Anthony Page, Christopher L Soles
Abstract: The relationship between ion transport and polymer dynamics is central to the pursuit of solid polymer electrolytes for lithium batteries. This understanding is critical to achieve solid polymer electrolyte systems of sufficiently high ion conductiv ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=910506

6. Understanding Interfacial Structure of Proton Exchange Membrane Fuel Cells
Published: 5/7/2012
Authors: Kirt Anthony Page, Sangcheol Kim, Christopher L Soles
Abstract: Although substantial improvements have been demonstrated for fuel cell technology over the past decade, the major technical challenges as associated with cost and durability should be overcome for fuel cells to compete in real markets and achieve wid ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=909432

7. A Robust and High-Throughput Measurement Platform for Monomer Reactivity Ratios from Surface-Initiated Polymerization
Published: 2/23/2012
Authors: Kirt Anthony Page, Derek Patton, Emily Hoff, Michael J Fasolka, Kathryn L Beers
Abstract: This article describes a robust approach to measure monomer reactivity ratios from surface-initiated copolymerization, by measuring composition of statistical copolymer brush surfaces using x-ray photoelectron spectroscopy. Statistical copolymer br ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=910460

8. Structure and Properties of Polymer Electrolyte Membranes Containing Phosphonic Acids for Anhydrous Fuel Cells
Published: 11/9/2011
Authors: Kirt Anthony Page, Christopher L Soles, Huagen H. Peng, Do Y. Yoon, Sung-Il Lee, Myeongsoo Song, Kyung-Hwan Yoon, Wolfgang Meyer
Abstract: Recently, water-free, proton conducting, polymer electrolytes are attracting attention due to their possible application as fuel cell membranes at intermediate temperatures (100 ºC to 200 ºC). Phosphonic acid groups are considered feasible anhydrous ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=908142

9. Hyperbranched Poly(ethylene oxide) Electrolytes for Lithium Ion Batteries
Published: 5/17/2011
Authors: Christopher L Soles, Kirt Anthony Page, Huagen H. Peng
Abstract: This work demonstrates the capability of hyper-branched PEO polymers to act as a polyelectrolyte for Li-ion batteries. Hyperbranching has been shown to lead to a 100 fold increase in the ion conductivity below the melting temperature of the PEO cryst ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=906562

10. Strain-Based Temperature Memory Effect for Nafion® and Its Molecular Origins
Published: 4/20/2011
Authors: Kirt Anthony Page, Scott Eastman, Tao Xie
Abstract: A shape memory polymer traditionally refers to a polymer that can memorize one temporary shape and recover to its permanent shape upon exposure to an external stimulus. Although this basic concept has been known for at least half a century, recent ad ...
http://www.nist.gov/manuscript-publication-search.cfm?pub_id=906317



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