Thompson, W.
and Jacox, M.
(2011),
The Infrared Spectrum of NN...CO+ Trapped in Solid Neon, Journal of Chemical Physics, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=909909
(Accessed October 10, 2025)
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The Infrared Spectrum of NN...CO+ Trapped in Solid Neon
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Abstract
Codeposition of a Ne:N2:CO = 200:1:1 mixture at 4.3 K with a beam of very pure neon atoms excited to their energy levels between 16.6 and 16.85 eV leads to stabilization in the resulting solid of sufficient NNCO+ for detection of its NN- and CO-stretching vibration fundamentals. Detailed isotopic substitution studies and density functional calculations for the various isotopologues support the identification of NNCO+ and permit estimation of the positions of two of its low-frequency fundamentals. A sufficient concentration of NOCN is also stabilized in the neon matrix for detection of its NO-stretching vibrational fundamental.Citation
Journal of Chemical Physics
Volume
135
Issue
22
Pub Type
Journals
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Keywords
density functional calculations, infrared spectrum, isotopic substitution, neon matrix, NOCN, NNCO cation
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Created December 14, 2011, Updated October 12, 2021