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|Author(s):||Warren E. Thompson; Marilyn E. Jacox;|
|Title:||The Infrared Spectrum of NN...CO+ Trapped in Solid Neon|
|Published:||December 15, 2011|
|Abstract:||Codeposition of a Ne:N2:CO = 200:1:1 mixture at 4.3 K with a beam of very pure neon atoms excited to their energy levels between 16.6 and 16.85 eV leads to stabilization in the resulting solid of sufficient NNCO+ for detection of its NN- and CO-stretching vibration fundamentals. Detailed isotopic substitution studies and density functional calculations for the various isotopologues support the identification of NNCO+ and permit estimation of the positions of two of its low-frequency fundamentals. A sufficient concentration of NOCN is also stabilized in the neon matrix for detection of its NO-stretching vibrational fundamental.|
|Citation:||Journal of Chemical Physics|
|Pages:||pp. 224307/1 - 224307/7|
|Keywords:||density functional calculations, infrared spectrum, isotopic substitution, neon matrix, NOCN, NNCO cation|
|Research Areas:||Molecular Physics|
|PDF version:||Click here to retrieve PDF version of paper (441KB)|