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Displaying 1 - 9 of 9

Study of the Reactions of OH with HCl, HBr, and HI between 298 K and 460 K.

November 24, 2020
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Igor Larin
The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 K to 460 K by using a discharge flow – electron paramagnetic resonance technique. The rate constants at room temperature were found to be kHCl(298 K) = (7.9

Photochemical Properties of Hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: Reactivity toward OH, IR Absorption Cross Sections, Atmospheric Lifetimes and Global Warming Potentials

September 22, 2014
Author(s)
Vladimir L. Orkin, Victor Khamaganov, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially fluorinated ethers, CH3OCF3 (kHFE-143a), CH3OCHF2 (kHFE-152a), and CHF2OCH2CF3 (kHFE-245fa), were measured using a discharge flow – electron paramagnetic resonance technique

Photochemical Properties of Some Cl-Containing Halogenated Alkanes

May 31, 2013
Author(s)
Vladimir L. Orkin, Victor Khamaganov, E. E. Kasimovskaya, A G. Guschin
Rate constants for the gas phase reactions of OH radicals with three partially halogenated alkanes, CHCl3 (kMC), CHFClCFCl2 (k122a), and CH2CFCl2 (k132c), were measured using a discharge flow – electron paramagnetic resonance technique over the temperature

2-Bromo-3,3,3-Trifluoropropene: OH Reaction Rate Constant, IR Absorption Spectrum, Ozone Depletion Potentials and Global Warming Potentials

December 30, 2011
Author(s)
Kenneth O. Patten, Victor Khamaganov, Vladimir L. Orkin, Steven L. Baughcum, Donald J. Wuebbles
The rate constant for the gas phase reaction of OH radicals with BTP (2-Bromo-3,3,3-trifluoropropene, CH2=CBrCF3) was measured using a flash photolysis resonance-fluorescence technique over the temperature range 220 K to 370 K. The Arrhenius plot was found

High Accuracy Measurements of OH Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols.

March 4, 2011
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the