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Displaying 1 - 25 of 86

STANDARD REFERENCE MATERIALS FOR THE POLYMERS INDUSTRY

May 24, 2016
Author(s)
Walter G. McDonough, Sara Orski, Charles M. Guttman, Kalman Migler, Kathryn L. Beers
The National Institute of Standards and Technology (NIST) provides science, industry, and government with a central source of well-characterized materials certified for chemical composition or for some chemical or physical property. These materials are

Automated Data Processing and Quantification in Polymer Mass Spectrometry

December 1, 2011
Author(s)
Till Gruendling, Christopher Barner-Kowollik, William E. Wallace, Charles M. Guttman, Anthony J. Kearsley
An overview is given of some new techniques in quantitative composition and molecular mass distribution measurement of synthetic polymers by mass spectrometry. New concepts in data analysis, including peak picking and integration, are also described.

CONTINUOUS FLOW ENZYME-CATALYZED POLYMERIZATION IN A MICROREACTOR

March 25, 2011
Author(s)
Santanu S. Kundu, Atul S. Bhangale, William E. Wallace, Kathleen M. Flynn, Charles M. Guttman, Richard Gross, Kathryn L. Beers
Enzymes immobilized on solid supports are increasingly used for chemical transformation because the process is greener and sustainable. Here we use microreactors to study enzyme catalyzed ring opening polymerization of -caprolactone to polycaprolactone. A

Molecular Mass Distribution Measurement by Mass Spectrometry

May 19, 2010
Author(s)
William E. Wallace, Charles M. Guttman
This NIST Recommended Practice Guide presents a method using mass spectrometry to make a quantitative determination of the molecular mass distribution of narrow polydispersity synthetic molecular materials. The main obstacle for converting an oligomer

A METHODOLOGY FOR DETECTING RESIDUAL PHOSPHORIC ACID IN POLYBENZOXAZOLE FIBERS

November 24, 2009
Author(s)
Eun S. Park, John R. Sieber, Charles M. Guttman, Kirk D. Rice, Kathleen M. Flynn, Stephanie S. Watson, Gale A. Holmes
There is great interest in the degradation of ballistic fibers from exposure to sunlight and high humidity, because it directly affects the lives of people who use protective ballistic armor. However, to date, no mechanism has been found to explain how

A Coherent Approach for Interrogating Polybenzoxazole Fibers for Residual Phosphoric Acid

September 17, 2009
Author(s)
Gale A. Holmes, Eun S. Park, Charles M. Guttman, Kathleen M. Flynn, John R. Sieber, Stephanie S. Watson, Kirk D. Rice
Because of the premature failure of soft-body armor that contains the active fiber poly [(benzo-[1,2-d:5,4-d']-benzoxazole-2,6-diyl)-1,4-phenylene] (PBO), the Office of Law Enforcement Standards (OLES) at the National Institute of Standards and Technology

Quantitative Measurement of the Polydispersity in the Extent of Functionalization of Glass Forming Resorcinarenes

May 1, 2009
Author(s)
William E. Wallace, Kathleen M. Flynn, Charles M. Guttman, David L. VanderHart, Vivek M. Prabhu, Anuja De Silva, Nelson Felix, Christopher K. Ober
The polydispersity in the degree of functionalization for two calix[4]resorcinarenes was determined by measuring their molecular mass distribution with matrix-assisted laser desorption/ionization time of flight mass spectrometry. A mathematical method for

Adhesive bonding to dentin improved by polymerizable cyclodextrin derivatives

January 5, 2009
Author(s)
Rafael L. Bowen, Gary E. Schumacher, Anthony A. Giuseppetti, Kathleen M. Flynn, Charles M. Guttman, Clifton M. Carey
Objectives. Determine bonding characteristics of a hydrophilic monomer formulation containing PCDs (Polymerizable Cyclodextrin Derivatives). The hypothesis was that a formulation containing hydrophilic cross-linking diluent comonomers and PCD molecules

High Temperature Light Scattering of Synthetic Polymers: A Practice Guide

October 16, 2008
Author(s)
Charles M. Guttman, J R. Maurey
The characterization of polymeric materials certified as NIST Standard Reference Materials, to provide such standards to science and industry, has continued at the NIST over an interval of four decades. Characterization of polyethylene SRM's by high

Numerical Optimization of Matrix-Assisted Laser Desorption/Ionization Time-of- Flight Mass Spectrometry: Application to Synthetic Polymer Molecular Mass Distribution Measurement

May 26, 2007
Author(s)
William E. Wallace, Charles M. Guttman, Kathleen M. Flynn, Anthony J. Kearsley
A novel approach is described for the selection of optimal instrument parameters that yield a mass spectrum which best replicates the molecular mass distribution of a synthetic polymer. The application of implicit filtering algorithms is shown to be a

Measurement of Single Wall Nanotube Dispersion by Size Exclusion Chromatography

May 9, 2007
Author(s)
Barry J. Bauer, Matthew Becker, Vardhan Bajpai, Jeffrey A. Fagan, Erik K. Hobbie, Kalman D. Migler, Charles M. Guttman, William R. Blair
The dispersion of nanotubes in solution is necessary in order to achieve the goal of sorting and manipulating nanotubes by length and type and to then prepare high quality monodisperse samples. A necessary step is the proper characterization of the

Development of NIST SRM 2881, an Absolute Molecular Mass Distribution Polymer Standard

September 1, 2006
Author(s)
William E. Wallace, Charles M. Guttman, Kathleen M. Flynn, Anthony J. Kearsley
We present a strategy to create an absolute molecular mass distribution polymer Standard Reference Material. To create a standard our methods must be free of operator bias (intentional or unintentional). The steps include sample preparation, instrument

Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry Interlaboratory Comparison of Mixtures of Polystyrene With Different End Groups: Statistical Analysis of Mass Fractions and Mass Moments

July 1, 2005
Author(s)
Charles M. Guttman, S Wetzel, Kathleen M. Flynn, B M. Fanconi, David L. VanderHart, William E. Wallace
A matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) interlaboratory comparison was conducted on mixtures of synthetic polymers having the same repeat unit and closely matching molecular mass distributions but with

A Numerical Method for Mass Spectral Data Analysis

January 31, 2005
Author(s)
Anthony J. Kearsley, William E. Wallace, Javier Bernal, Charles M. Guttman
The new generation of mass spectrometers produces an astonishing amount of high-quality data in a brief period of time leading to inevitable data analysis bottlenecks. Automated data analysis algorithms are required for rapid and repeatable processing of