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Physics

Thermodynamics

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Displaying 501 - 525 of 830

Recommended vapor pressure and thermophysical data for ferrocene

August 14, 2012
Author(s)
Michal Fulem, Kvetoslav Ruzicka, Marisa A. Rocha, Luis M.N.B.F. Santos, Robert F. Berg
Recommended vapor pressure data for ferrocene (CAS Registry Number: 102-54-5) in the temperature range from 242 to 447 K were developed by the simultaneous correlation of critically assessed vapor pressures, heat capacities of the crystalline phase and the

Chemical and Thermophysical Characterization of 1,3,5-triisopropylcyclohexane

July 17, 2012
Author(s)
Thomas J. Bruno, Tara J. Fortin, Tara M. Lovestead, Jason A. Widegren
The complex nature of finished fuels makes definitive studies on composition and combustion properties very difficult and uncertain. This has led to the adoption of fuel surrogate mixtures in such studies. The development of a surrogate mixture is itself a

The Decomposition of 2-Pentyl and 3-Pentyl Radicals

July 15, 2012
Author(s)
Jeffrey A. Manion, Iftikhar A. Awan
The isomerization and decomposition reactions of 2-pentyl and 3-pentyl radicals have been studied in a single-pulse shock tube over a temperature range of 973 K to 1121 K and pressures of 120 kPa to 800 kPa. The results represent the first direct study of

Thermodynamic Properties of o-Xylene, m-Xylene, p-Xylene, and Ethylbenzene

June 27, 2012
Author(s)
Eric W. Lemmon, Yong Zhou, Jiangtao Wu
Equations of state for the xylene isomers (o-xylene, m-xylene, and p-xylene) and ethylbenzene have been developed with the use of the Helmholtz energy as the fundamental property with independent variables of density and temperature. The general

ThermoData Engine (TDE) Version 7.0 (Pure compounds, Binary Mixtures, Ternary Mixtures, Chemical Reactions) Standard Reference Database 103b

June 11, 2012
Author(s)
Michael D. Frenkel, Robert D. Chirico, Vladimir Diky, Chris D. Muzny, Andrei F. Kazakov, Joe W. Magee, Ilmutdin M. Abdulagatov, Kenneth G. Kroenlein, Carlos A. Diaz-Tovar, Jeong W. Kang, Rafiqul Gani
The first full-scale software implementation of the dynamic data evaluation concept {ThermoData Engine (TDE)} is described for thermophysical and thermochemical property data. This concept requires the development of large electronic databases capable of

Saturation molalities and standard molar enthalpies of solution of alpha-D-xylose(cr) in H2O(l); Standard molar enthalpies of solution of 1,4-beta-D-xylobiose(am), and 1,4-beta-D-xylotriose(am) in H2O(l)

May 14, 2012
Author(s)
Robert N. Goldberg, Brian E. Lang, Bruce Coxon, Stephen R. Decker
The saturation molality of alpha-D-xylose(cr) in water was measured by using HPLC and is m(sat) = (8.43 ± 0.42) mol∙kg-1 at the temperature T = 298.15 K. It was also established that the anhydrous form of alpha-D-xylose(cr) is the crystalline form that is

Guidelines for reporting of phase equilibrium measurements (IUPAC Recommendations 2012)

April 27, 2012
Author(s)
Robert D. Chirico, Theodoor W. de Loos, Juergen Gmehling, Anthony R. Goodwin, Sumnesh Gupta, Kenneth N. Marsh, Calvin Spencer, Martin P. Trusler, William M. Haynes, Vicente Rives, Joan F. Brennecke
Recommendations are given for reporting in the primary scientific literature of measurements involving phase equilibrium. The focus is on documentation issues, and many of the recommendations may also be applied to the more general fields of thermodynamic

ThermoData Engine (TDE): Software Implementation of the Dynamic Data Evaluation Concept. 7. Ternary Mixtures

January 27, 2012
Author(s)
Vladimir Diky, Robert D. Chirico, Chris D. Muzny, Andrei F. Kazakov, Kenneth G. Kroenlein, Joe W. Magee, Ilmutdin M. Abdulagatov, Jeongwon J. Kang, Michael D. Frenkel
ThermoData Engine (TDE) is the first full-scale software implementation of the dynamic data evaluation concept, as reported in this journal. The present paper describes the first application of this concept to the evaluation of thermophysical properties for
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