Liu, L.
, Bearden, D.
and Rein, K.
(2011),
Biosynthetic origin of the 3-amino-2,5,7,8-tetrahydroxy-10-methylundecanoic acid moiety and absolute configuration of pahayokolides A and B, Journal of Natural Products
(Accessed April 18, 2024)
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Biosynthetic origin of the 3-amino-2,5,7,8-tetrahydroxy-10-methylundecanoic acid moiety and absolute configuration of pahayokolides A and B
Published
Author(s)
Li Liu, , Kathleen S. Rein
Abstract
Pahayokolide A is a cyclic undecapeptide from the cyanobacterium Lyngbya sp. The absolute configurations of the amino acids of pahayokolide A have been determined. Pahayokolide A contains the unusual α-hydroxy-β-amino acid, 3-amino-2,5,7,8- tetrahydroxy-10-methylundecanoic acid (Athmu). The starter unit for the biosynthesis of Athmu is derived from leucine which is extended further with three acetate units.Citation
Journal of Natural Products
Volume
74
Issue
6
Pub Type
Journals
Keywords
cyanobacteria, natural product, NMR, spectroscopy
Citation
Created June 7, 2011, Updated October 12, 2021