We introduce a new technique (SIEBIMM) for high-throughput measurements
of the mechanical properties of thin polymeric films. This technique
relies upon a highly periodic strain-induced buckling instability that
arises from a mismatch of the moduli of a relatively stiff polymer coating
on a soft silicone sheet. The modulus-dependent buckling wavelength,
typically (1 to 10) microns for 100 nm thick glassy films, is measured
rapidly by conventional light scattering. The SIEBIMM-measured modulus
is shown to agree with that measured by conventional Instron-like techniques.
We show directly that the buckling instability is highly sinusoidal for
low strains thereby insuring the suitability of simple mechanical analysis.
Utilizing our expertise in preparing thickness gradients by flow coating,
we demonstrate that the flexural rigidities of thin films having a wide
range of thicknesses can be measured in minutes. By measuring the
temporal decay of strain-induced diffraction peaks for plasticized coatings,
we show that this technique can evaluate viscoelastic properties, such
as creep. We also show that a large amount of strain induces cracking in
films, resulting in an optical signature where the scattering intensity
decays smoothly with wavenumber. We demonstrate SIEBIMMÕs capability
with several academic and industrially-relevant polymeric systems, including
polystyrene loaded with a wide range of plasticizer, a blend of block copolymers
with polystyrene and polyisoprene blocks, and a thiolene-based ultraviolet
curing adhesive.