Take a sneak peek at the new NIST.gov and let us know what you think!
(Please note: some content may not be complete on the beta site.).
Hall Effect NavigationMain PageI. IntroductionII. The Hall EffectIII. Resistivity and Hall MeasurementsIV. AlgorithmV. ReferencesLeave CommentsView CommentsFigure 1Figure 2Figure 3Figure 4

III. Resistivity and Hall MeasurementsDefinitions for Resistivity Measurements Definitions for Hall Measurements The following procedures for carrying out Hall measurements provide a guideline for the beginning user who wants to learn operational procedures, as well as a reference for experienced operators who wish to invent and engineer improvements in the equipment and methodology. It is preferable to fabricate samples from thin plates of the semiconductor material and to adopt a suitable geometry, as illustrated in Fig. 4. The average diameters (D) of the contacts, and sample thickness (d) must be much smaller than the distance between the contacts (L). Relative errors caused by nonzero values of D are of the order of D/L. The following equipment is required:
Definitions for Resistivity Measurements Four leads are connected to the four ohmic contacts on the sample. These are labeled 1, 2, 3, and 4 counterclockwise as shown in Fig. 4a. It is important to use the same batch of wire for all four leads in order to minimize thermoelectric effects. Similarly, all four ohmic contacts should consist of the same material. We define the following parameters (see Fig. 2): ρ = sample resistivity (in Ω·cm) d = conducting layer thickness (in cm) I_{12} = positive dc current I injected into contact 1 and taken out of contact 2. Likewise for I_{23}, I_{34}, I_{41}, I_{21}, I_{14}, I_{43}, I_{32} (in amperes, A) V_{12} = dc voltage measured between contacts 1 and 2 (V_{1}  V_{2}) without applied magnetic field (B = 0). Likewise for V_{23}, V_{34}, V_{41}, V_{21}, V_{14}, V_{43}, V_{32} (in volts, V) The data must be checked for internal consistency, for ohmic contact quality, and for sample uniformity.
Eight measurements of voltage yield the following eight values of resistance, all of which must be positive:
Note that with this switching arrangement the voltmeter is reading only positive voltages, so the meter must be carefully zeroed. Because the second half of this sequence of measurements is redundant, it permits important consistency checks on measurement repeatability, ohmic contact quality, and sample uniformity.
If any of the above fail to be true within 5 % (preferably 3 %), investigate the sources of error.
via the van der Pauw equation [Eq. (3)]. For numerical solution of Eq. (3), see the routine in Section IV. If the conducting layer thickness d is known, the bulk resistivity ρ = R_{S} d can be calculated from R_{S}. Definitions for Hall Measurements The Hall measurement, carried out in the presence of a magnetic field, yields the sheet carrier density n_{s} and the bulk carrier density n or p (for ntype or ptype material) if the conducting layer thickness of the sample is known. The Hall voltage for thick, heavily doped samples can be quite small (of the order of microvolts). The difficulty in obtaining accurate results is not merely the small magnitude of the Hall voltage since good quality digital voltmeters on the market today are quite adequate. The more severe problem comes from the large offset voltage caused by nonsymmetric contact placement, sample shape, and sometimes nonuniform temperature. The most common way to control this problem is to acquire two sets of Hall measurements, one for positive and one for negative magnetic field direction. The relevant definitions are as follows (Fig. 3): I_{13} = dc current injected into lead 1 and taken out of lead 3. Likewise for I_{31}, I_{42}, and I_{24}. B = constant and uniform magnetic field intensity (to within 3 %) applied parallel to the zaxis within a few degrees (Fig .3). B is positive when pointing in the positive z direction, and negative when pointing in the negative z direction. V_{24P} = Hall voltage measured between leads 2 and 4 with magnetic field positive for I_{13}. Likewise for V_{42P}, V_{13P}, and V_{31P}. Similar definitions for V_{24N}, V_{42N}, V_{13N}, and V_{31N} apply when the magnetic field B is reversed. The procedure for the Hall measurement is:
The above eight measurements of Hall voltages V_{24P}, V_{42P}, V_{13P}, V_{31P}, V_{24N}, V_{42N}, V_{13N}, and V_{31N} determine the sample type (n or p) and the sheet carrier density n_{s}. The Hall mobility can be determined from the sheet density n_{s} and the sheet resistance R_{S} obtained in the resistivity measurement. See Eq. (2). This sequence of measurements is redundant in that for a uniform sample the average Hall voltage from each of the two diagonal sets of contacts should be the same. Steps for the calculation of carrier density and Hall mobility are:
where B is the magnetic field in gauss (G) and I is the dc current in amperes (A).
The procedure for this sample is now complete. The final printout might contain (Sample Hall Worksheet):
