Fabrication of nanoporous organosilicate low-k dielectric materials and characterization techniques including synthesis and characterization of organosilicate materials.
Direct patterning and creating functional patterns using nanoimprint lithography and characterization.
Pattern shape characterization using X-ray and Neutron reflectivity.
Relaxation behavior of polymeric pattern correlated with patterning process.
Silsesquioxane-based organosilicate
materials
Nanoporous organosilicate thin films
Nanoporous organosilicate patterns
directly fabricated from NIL
Secondary molds for UV and thermal NIL
from organosilicate materials
Bulk heterojunction (BHJ) structures for organic photovoltaic
application.
Highly ordered organosilicates thin film
structures templated by block copolymers
Nanoscale polymeric pattern stability.
Representative
Publications
"Novel inorganic-organic hybrid block copolymers as
pore generators for nanoporous ultralow-dielectric-constant films", H.
W. Ro, K. J. Kim, P. Theato, D. W. Gidley, D. Y. Yoon, Macromolecules 38,
1031 (2005).
"High-modulus spin-on organosilicate glasses for
nanoporous applications", H. W. Ro, K. Char, E.-c. Jeon, H.-J.
Kim, D. Kwon, H.-J. Lee, J.-K. Lee, H.-W. Rhee, C. L. Soles, D. Y. Yoon, Adv.
Mater. 19, 705 (2007).
"The
Direct Patterning of Nanoporous Interlayer Dielectric Insulator Films by
Nanoimprint Lithography", H. W. Ro, R. L. Jones, H. Peng, D. R. Hines,
H.-J. Lee, E. K. Lin, A. Karim, D. Y. Yoon, D. W. Gidley, C. L. Soles, Adv.
Mater. 19, 2919 (2007).
"Self-Sealing
of Nanoporous Low Dielectric Constant Patterns Fabricated by Nanoimprint
Lithography", H. W. Ro, H. Peng, K.-i. Niihara, H.-J. Lee, E. K. Lin, A.
Karim, D. W. Gidley, H. Jinnai, D. Y. Yoon, C. L. Soles, Adv. Mater. 20,
1934 (2008).
Position:
Polymer Chemist, NIST Associate
Polymers Division
Electronics Materials Group